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橄榄油与菜籽油调和比例对花椒油风味及营养成分的影响

Effect of Blending Ratio of Olive Oil and Rapeseed Oil on the Flavor and Nutritional Components of Sichuan Pepper Oil

  • 摘要: 为了研究橄榄油与菜籽油的调和比例对花椒油挥发性物质及营养成分的影响,利用气相色谱(Gas chromatography,GC)和离子迁移谱(Ion mobility spectrometry,IMS)联用技术对7个花椒油样品(纯橄榄花椒油GL、纯菜籽花椒油AJ、花椒油1-9(菜籽∶橄榄=1∶9)、花椒油3-7(菜籽∶橄榄=3∶7)、花椒油5-5(菜籽∶橄榄=5∶5)、花椒油6-4(菜籽∶橄榄=6∶4)、花椒油8-2(菜籽∶橄榄=8∶2))中的挥发性成分进行采集和分析。结果表明:不同花椒油都有各自的特征峰区域,GL的特征风味物质主要是糠醛、乙酸异丁酯、乙酸乙酯、3-甲基丁醛、正已醇,AJ的特征风味物质有二烯丙基二硫化物、柠檬烯、正戊醇、丙酸、E,E-2,4-庚二烯醛、乙酸-3-甲基丁酯、羟基丙酮、2-庚酮等;根据指纹图谱及主成分分析发现,与GL风味最为接近的是花椒油1-9,与AJ风味最为接近的是花椒油8-2;GL中角鲨烯含量为2 912.11 mg/kg,花椒油3-7、5-5、6-4、8-2中角鲨烯含量均极显著低于GL(P<0.01);GL中甾醇含量为1 427.56 mg/kg,花椒油5-5、6-4、8-2中甾醇含量均显著高于GL(P<0.05);6个橄榄花椒油样品中的α-生育酚含量均无显著差异。可见,花椒油中的挥发性物质、营养成分与菜籽油-橄榄油的调和比例密切相关,本研究结果可为菜籽-橄榄花椒调和油的调和比例提供数据参考。

     

    Abstract: In order to explore the effect of blending ratio of olive oil and rapeseed oil on the flavor and nutritional components of Sichuan pepper oil, the volatile components of seven samples of Sichuan pepper oil were collected and analyzed by Gas chromatography(GC) combined with Ion mobility spectroscopy(IMS), including pure olive Sichuan pepper oil(GL), pure rapeseed Sichuan pepper oil(AJ), Sichuan pepper oil 1-9(rapeseed oil ∶olive oil =1∶9), Sichuan pepper oil 3-7(rapeseed oil∶olive oil = 3∶7), Sichuan pepper oil 5-5(rapeseed oil∶olive oil = 5∶5),Sichuan pepper oil 6-4(rapeseed oil∶olive oil = 6∶4), Sichuan pepper oil 8-2(rapeseed oil∶olive oil = 8∶2). The results showed that different Sichuan pepper oil had their own characteristic peak regions, the main flavor compounds of GL were furfrual, isobutyl acetate, ethyl acetate and 3-methylbutyraldehyde and hexanol, the characteristic flavor compounds of AJ were diallyl disulfide, limonene, 1-pentanol, propionic acid, E,E-2,4-heptadienal, 3-methylbutyl acetate, hydroxyacetone, 2-heptanone, etc. According to the fingerprint and principal component analysis, pepper oil1-9 had the closest flavor to GL, pepper oil 8-2 had the closest flavor to AJ. The content of squalene in GL was2 912.11 mg/kg, and squalene contents in 3-7, 5-5, 6-4 and 8-2 were all significantly lower than that in GL(P<0.01). The content of sitosterol in GL was 1 427.56 mg/kg, sitosterol contents in pepper oil 5-5, 6-4 and 8-2 were significantly higher than that in GL(P<0.05). There was no significant difference in the content of α-tocopherol in six Zanthoxylum olive oil samples. In conclusion, the volatile compounds and nutrients in Sichuan pepper oil were closely related to the blending ratio of rapeseed oil to olive oil, which could provide data reference for the blending ratio of rapeseed-olive and zanthoxylum oil.

     

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