Abstract: The CsH2s-α,ω-bis(abietyl hydroxy propyl triethylenediamine chloride), here s=2,had been synthesized by reacting 3-abietylacyloxy-2-hydroxypropyl chloride with triethylenediamine at a yield of 50.71% and purity of 95.03%. The intermediate compound 3-abietylacyloxy-2-hydroxypropyl chloride was prepared from rosin(acid value 170.54 mg/g) reacted with epoxy chloropropane, and the esterification rate was 99.18%. The synthesis condition of the aimed compound was as follows:n(intermediate compound):n(triethylene diamines)1.5:1, reaction temperature 80℃ and reaction time 25 h. The structure of the aimed compound was characterized by FT-IR and its property was analyzed. The results showed that:emulsifying ability was up to 10 min, critical micelle concentration (cmc) was 9.7×10-4 mol/L and surface tension was 43.41 mN·m.The aimed compound maintained strong foaming ability and superior foaming stability.