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固体氧化物燃料电池新型阳极燃料的研究进展

魏胜利, 马万达, 杜振华, 杨帆

魏胜利, 马万达, 杜振华, 杨帆. 固体氧化物燃料电池新型阳极燃料的研究进展[J]. 江苏大学学报(自然科学版), 2023, 44(2): 151-158.
引用本文: 魏胜利, 马万达, 杜振华, 杨帆. 固体氧化物燃料电池新型阳极燃料的研究进展[J]. 江苏大学学报(自然科学版), 2023, 44(2): 151-158.
WEI Sheng-li, MA Wan-da, DU Zhen-hua, YANG Fan. Research progress of new anode fuels for solid oxide fuel cells[J]. Journal of Jiangsu University(Natural Science Edition), 2023, 44(2): 151-158.
Citation: WEI Sheng-li, MA Wan-da, DU Zhen-hua, YANG Fan. Research progress of new anode fuels for solid oxide fuel cells[J]. Journal of Jiangsu University(Natural Science Edition), 2023, 44(2): 151-158.

固体氧化物燃料电池新型阳极燃料的研究进展

基金项目: 

国家重点研发计划新能源汽车专项(2017YFB0103400)

详细信息
    作者简介:

    魏胜利(1978—),男,陕西凤翔人,教授(weishengli@ujs.edu.cn),主要从事动力机械高效低碳清洁燃烧的研究;马万达(1997—),男,河北沧州人,硕士研究生(mawd1997@163.com),主要从事固体氧化物燃料电池动力系统的研究

  • 中图分类号: TM911.4

Research progress of new anode fuels for solid oxide fuel cells

  • 摘要: 为了解决传统的氢气、一氧化碳等工业制气作为固体氧化物燃料电池(solid oxide fuel cell, SOFC)阳极燃料时,其在制备、存储、使用安全性等方面的问题,探究新型阳极燃料的研究及应用,以期在保证电池性能的同时实现SOFC的低碳甚至零碳排放.对当前有关SOFC新型阳极燃料的研究现状进行了调研总结,概述了SOFC的基本原理,阐明了国内外能源结构的影响.调研了低碳/零碳燃料在SOFC研究中的应用情况,包括甲烷等低碳烷烃、氨、生物质燃料、含碳类固体燃料等.在此基础上对阳极低碳/零碳燃料下SOFC联合动力系统的研究进行了概括总结,并指出了SOFC的发展方向.
    Abstract: To solve the problems in preparation, storage and use security of traditional industrial gases with hydrogen and carbon monoxide used as anode fuels of solid oxide fuel cell(SOFC), the new types of anode fuels were explored to achieve low-carbon or even zero-carbon emissions of SOFC while maintaining battery performance. The current research on new anode fuels of SOFC was surveyed, and the basic principle of SOFC was summarized, while the influence of foreign and domestic energy structure was also clarified. The application of low-carbon/zero-carbon fuels in SOFC research was investigated, including methane and other low-carbon alkanes, ammonia, biomass fuels, carbon containing solid fuels, etc. The research of SOFC hybrid power system under low-carbon/zero-carbon fuel was generalized, and the development direction of SOFC was pointed out.
  • [1]

    WANG H,ANG B W.Assessing the role of internatio-nal trade in global CO2 emissions:an index decomposition analysis approach[J].Applied Energy,2018,218:146-158.

    [2] 刘洁,王菊香,邢志娜,等.燃料电池研究进展及发展探析[J].节能技术,2010,28(4):364-368.LIU J,WANG J X,XING Z N,et al.The investigation on research progress and development of fuel cell[J].Energy Conservation Technology,2010,28(4):364-368.(in Chinese)
    [3] 荆波,吕喆,许大鹏,等.中温SOFC阴极材料La0.7Sr0.3Co1-xCuxO3-δ 的制备及性能[J].吉林大学学报(理学版),2005,43(5):650-653.JING B,LYU Z,XU D P,et al.Preparation and performance of cathode materials of La0.7Sr0.3Co1-xCuxO3-δ for IT-SOFC[J].Journal of Jilin University (Science Edition),2005,43(5):650-653.(in Chinese)
    [4]

    SUN C W,STIMMING U.Recent anode advances in solid oxide fuel cells[J].Journal of Power Sources,2007,171(2):247-260.

    [5] 于雯珺.H2/CO为燃料的中温固体氧化物燃料电池Ni基阳极制备及改性研究[D].哈尔滨:哈尔滨工业大学,2019.
    [6]

    YANG X Y,ZHAO H B,HOU Q L.Proposal and thermodynamic performance study of a novel LNG-fueled SOFC-HAT-CCHP system with near-zero CO2 emissions[J].International Journal of Hydrogen Energy,2020,45(38):19691-19706.

    [7] 曹静,王小博,孙翔,等.基于固体氧化物燃料电池的高效清洁发电系统[J].南方能源建设,2020,7(2):28-34.CAO J,WANG X B,SUN X,et al.High-efficiency clean power generation system based on solid oxide fuel cell[J].Southern Energy Construction,2020,7(2):28-34.(in Chinese)
    [8] bp公司.bp世界能源统计年鉴2021[EB/OL].(2021-07-08)[2022-12-20]. https://www.bp.com.cn/content/dam/bp/country-sites/zh_cn/china/home/reports/statistical-review-of-world-energy/2021/BP_Stats_2021.pdf.
    [9] bp公司.bp世界能源展望2022[EB/OL].(2022-03-14)[2022-12-20]. https://www.bp.com.cn/content/dam/bp/country-sites/zh_cn/china/home/reports/bp-energy-outlook/2022/energy-outlook-2022-edition-cn.pdf.
    [10] 韩松.中国能源结构与产业结构发展现状及灰色关联关系研究[J].工程建设标准化,2020(7):69-79.HAN S.The grey correlation analysis of China′s energy structure and industrial structure[J].Standardization of Engineering Construction,2020(7):69-79.(in Chinese)
    [11] 阿迪里麦提·萨力木.能源结构的发展现状及其改善方法的探究[J].化学工程与装备,2016(3):162-164.SALIM A M.Development status and improvement methods of energy structure[J].Chemical Engineering & Equipment,2016(3):162-164.(in Chinese)
    [12]

    KÜMÜK B,LBAŞ M.Coal gas fuel utilization effects on electrolyte supported solide oxide fuel cell perfor-mance[J].International Journal of Hydrogen Energy,2021,46(57):29523-29528.

    [13]

    ATSONIOS K,SAMLIS C,MANOU K,et al.Technical assessment of LNG based polygeneration systems for non-interconnected island cases using SOFC[J].International Journal of Hydrogen Energy,2021,46(6):4827-4843.

    [14] 张锋.页岩气工业开发现状和对策研究[J].石化技术,2021,28(4):134-135.ZHANG F.Research on development status and countermeasures of shale gas industry[J].Petrochemical Industry Technology,2021,28(4):134-135.(in Chinese)
    [15]

    LO FARO M,ANTONUCCI V,ANTONUCCI P L,et al.Fuel flexibility:a key challenge for SOFC technology[J].Fuel,2012,102:554-559.

    [16]

    CINTI G,DESIDERI U.SOFC fuelled with reformed urea[J].Applied Energy,2015,154:242-253.

    [17]

    TU B F,WEN H,YIN Y X,et al.Thermodynamic analysis and experimental study of electrode reactions and open circuit voltages for methane-fuelled SOFC[J].International Journal of Hydrogen Energy,2020,45(58):34069-34079.

    [18]

    ZHANG Y L,XU N,FAN H,et al.La0.6Sr0.4Co0.2-Fe0.8O3-δ nanoparticles modified Ni-based anode for direct methane-fueled SOFCs[J].Energy Procedia,2019,158:2250-2255.

    [19]

    LIU Y Y,JIA L C,LI J,et al.High-performance Ni in-situ exsolved Ba(Ce0.9Y0.1)0.8Ni0.2O3-δ/Gd0.1Ce0.9-O1.95 composite anode for SOFC with long-term stability in methane fuel[J].Composites Part B:Engineering,doi: 10.1016/j.compositesb.2020.108033.

    [20]

    WAN Z J,TAO Y K,SHAO J,et al.Ammonia as an effective hydrogen carrier and a clean fuel for solid oxide fuel cells[J].Energy Conversion and Management,doi: 10.1016/j.enconman.2020.113729.

    [21]

    PERNA A,MINUTILLO M,JANNELLI E,et al.Design and performance assessment of a combined heat,hydrogen and power (CHHP) system based on ammonia-fueled SOFC[J].Applied Energy,2018,231:1216-1229.

    [22]

    HASHINOKUCHI M,ZHANG M J,DOI T,et al.Enhancement of anode activity and stability by Cr addition at Ni/Sm-doped CeO2 cermet anodes in NH3-fueled solid oxide fuel cells[J].Solid State Ionics,2018,319(1):180-185.

    [23]

    YILDIZ K,IBRAHIM D.Analysis and performance assessment of NH3 and H2 fed SOFC with proton-conducting electrolyte[J].International Journal of Hydrogen Energy,2018,43(11):5795-5807.

    [24] 马万达,魏胜利,杜振华,等.零碳/低碳燃料SOFC-发动机联合动力系统热力学分析[J/OL].西安交通大学学报. http://kns.cnki.net/kcms/detail/61.1069.T.20220727.1143.002.html.MA" target="_blank"> http://kns.cnki.net/kcms/detail/61.1069.T.20220727.1143.002.html.MA W D,WEI S L,DU Z H,et al.Thermodynamic analysis for none-carbon and low-carbon fuel on SOFC-engine hybrid power system[J/OL].Journal of Xi′an Jiaotong University. http://kns.cnki.net/kcms/detail/61.1069.T.20220727.1143.002.html.(in Chinese)
    [25]

    SHI H G,LI Q J,TAN W Y,et al.Solid oxide fuel cells in combination with biomass gasification for electric power generation[J].Chinese Journal of Chemical Engineering,2020,28(4):1156-1161.

    [26]

    LIN J F,THOMAS A T,WALLUK M R,et al.Bio-fuel reformation for solid oxide fuel cell applications,part 3:biodiesel-diesel blends[J].International Journal of Hydrogen Energy,2014,39(1):196-208.

    [27]

    GADSBOLL R ∅,THOMSEN J,BANG-MOLLER C,et al.Solid oxide fuel cells powered by biomass gasification for high efficiency power generation[J].Energy,2017,131(1):198-206.

    [28]

    DAMERGI E,MADI H,SHARMA S,et al.A combined hydrothermal gasification-solid oxide fuel cell system for sustainable production of algal biomass and energy[J].Algal Research,doi: 10.1016/j.algal.2019.101552.

    [29]

    SANTIN M,TRAVERSO A,MAGISTRI L.Liquid fuel utilization in SOFC hybrid systems[J].Applied Energy,2009,86(10):2204-2212.

    [30] 田文涛.以碳氢化合物为燃料的固体氧化物燃料电池性能研究[D].南京:东南大学,2019.
    [31] 徐凯.固体氧化物直接碳燃料电池阳极反应机理及电化学性能研究[D].武汉:华中科技大学,2017.
    [32]

    WU H,XIAO J,ZENG X Y,et al.A high performance direct carbon solid oxide fuel cell-a green pathway for brown coal utilization[J].Applied Energy,2019,248:679-687.

    [33]

    XIE Y M,LI J L,HOU J X,et al.Direct use of coke in a solid oxide fuel cell[J].Journal of Fuel Chemistry and Technology,2018,46(10):1168-1174.

    [34]

    MA M J,YANG X X,QIAO J S,et al.Progress and challenges of carbon-fueled solid oxide fuel cells anode[J].Journal of Energy Chemistry,2021,56(5):209-222.

    [35]

    YU F Y,HAN T T,WANG Z G,et al.Recent progress in direct carbon solid oxide fuel cell:advanced anode catalysts,diversified carbon fuels,and heat management[J].International Journal of Hydrogen Energy,2021,46(5):4283-4300.

    [36]

    KONG W,HAN Z,LU S Y,et al.A simple but effective design to enhance the performance and durability of direct carbon solid oxide fuel cells[J].Applied Energy,doi: 10.1016/j.apenergy.2021.116586.

    [37]

    SANTIN M,TRAVERSO A,MAGISTRI L,et al.Thermoeconomic analysis of SOFC-GT hybrid systems fed by liquid fuels[J].Energy,2009,35(2):1077-1083.

    [38]

    WU Z,TAN P,ZHU P F,et al.Performance analysis of a novel SOFC-HCCI engine hybrid system coupled with metal hydride reactor for H2 addition by waste heat recovery[J].Energy Conversion and Management,2019,191:119-131.

    [39]

    REYHANI H A,MERATIZAMAN M,EBRAHIMI A,et al.Thermodynamic and economic optimization of SOFC-GT and its cogeneration opportunities using gene-rated syngas from heavy fuel oil gasification[J].Energy,2016,107:141-164.

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  • 收稿日期:  2021-06-02
  • 刊出日期:  2023-03-09

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