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生物质催化转化制备生物基航空燃料的研究进展

A Review on Recent Advances in Catalytic Conversion of Biomass for Selective Production of Bio-aviation Fuels

  • 摘要: 生物质催化转化是制备高品质生物基航空燃料和解决能源危机的主要途径,本文从现有的生物基航空燃料的制备方法出发,从适应需求的原料和技术路线的角度,概述了油脂、木质纤维、糖类等不同的原料所需的技术路线和催化体系,以及加氢脱氧、费-托合成、羟醛缩合、烯烃齐聚等不同技术路线所用的催化剂,同时对反应条件以及反应机理进行优化和探索,并指明催化转化过程中存在成本高、工艺和转化机理复杂(高温和高压)、H2用量高、目标产物的选择性较差以及催化剂失活等问题。最后,针对各种原料、技术路线的优缺点以及面临的问题,提出了建议并展望其未来发展方向。

     

    Abstract: Catalytic conversion of biomass was the main route to produce high quality bio-based aviation fuel and solve energy crisis. In this paper, according to the perspective of the existing preparation methods of bio-aviation fuel, the technical routes and catalytic systems required by different feedstocks and the catalysts used in different technical routes were summarized from the perspective of raw materials adapted to the demand(oil, lignocellulose biomass and sugar raw materials) and technical routes(hydrodeoxygenation, Fischer-Tropsch synthesis, aldol condensation and olefin oligomerization). At the same time, the reaction conditions and reaction mechanism were also reported. It was pointed out that the critical problems in catalytic conversion process, including higher cost, complex process and conversion mechanism(high temperature and high pressure), higher H2 consumption, poor selectivity of desired target products and deactivation of catalyst. Finally, according to the advantages and disadvantages of various raw materials and technical routes as well as the problems faced, some suggestions were proposed and the future development direction was prospected.

     

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