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磺甲基化乙酸木质素制备农药分散剂及其性能评价

Preparation of Pesticide Dispersant from Acetic Acid Lignin and Performance Evaluation

  • 摘要: 用不同质量分数乙酸对乙酸木质素(AAL)进行分级,得到不同相对分子质量的4个级分(AAL-1~AAL-4)。通过磺甲基化改性,以AAL-1~AAL-4为原料,制得不同相对分子质量的磺甲基化木质素(SML)样品SML-1~SML-4;以AAL-2为原料,添加不同用量的无水亚硫酸钠制备不同磺酸基含量的磺甲基化木质素SML-A~SML-D,并将其作为农药分散剂,制备40%腈菌唑可湿性粉剂(WP),探讨了SML相对分子质量和磺酸基含量对40%腈菌唑WP应用性能的影响。研究结果表明:当SML的重均相对分子质量从5 768提高到13 964,腈菌唑悬浮率从72.68%升至83.69%,润湿时间从45 s升至62 s;当磺酸基从0.51 mmol/g增加到1.78 mmol/g,腈菌唑悬浮率从73.56%升至84.86%,润湿时间从72 s降至57 s。随着相对分子质量和磺酸基含量提高,40%腈菌唑WP悬浮液分散相的平均粒径降低,分散性较好;但过高的相对分子质量反而使腈菌唑悬浮率下降。

     

    Abstract: Acetic acid lignin(AAL) was fractionated by dissolution in aqueous solution of acetic acid with various mass fraction. Four fractions with different relative molecular weight, which were chosen from the fractionation products, were sulfomethylated to obtain products with different relative molecular weight and sulfonic group content. The sulfomethylated lignin(SML) was added into myclobutanil as a pesticide dispersant to get a 40% myclobutanil wettable powder(WP). The influence of relative molecular weight and sulfonic group content on the application performance of 40% myclobutanil wettable powder was investigated. The results indicated that the suspension rate of myclobutanil increased from 72.68% to 83.69% and the wetting time increased from 45 s to 62 s when the average molecular weight increased from 5 768 to 13 964. The suspension rate of myclobutanil increased from 73.56% to 84.86% and the wetting time decreased from 72 s to 57 s when the sulfonic group increased from 0.51 mmol/g to 1.78 mmol/g. The average particle size of the dispersed phase of a 40% myclobutanil WP decreased when the relative molecular weight and sulfonic group content increased. However, too high relative molecular weight resulted in a decrease of the suspension rate of myclobutanil.

     

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