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水性粘缸剂的制备及表征

Preparation and Characterization of Waterborne Creping Adhesive

  • 摘要: 在己二酸与二乙烯三胺合成水性聚酰胺PA236的基础上,将水性环氧树脂接枝到PA236上,得到改性PA236(PA236G),然后向PA236G中加入一定量的羟乙基纤维素溶液和水性固化剂906,制得水性粘缸剂CA514。采用红外、核磁氢谱、碳谱和凝胶色谱分析对PA236和改性PA236的结构和相对分子质量进行了表征,证实了PA236的成功合成以及水性环氧树脂的成功接枝;用热重分析测定了二者的热性能,表明二者均可用作粘缸剂的原料使用。对CA514所形成的薄膜性能进行了测试,结果表明:CA514烘干后形成的薄膜与市售产品(改性PAE)具有相似的性质,且耐水性更好,平均溶胀度可达188.3%;CA514可提供的平均剪切强度可达122.4 kPa,为市售产品的2倍多,基材附着力为136.6 N,约为市售产品的1.4倍。薄膜良好的耐水性能和力学性能说明CA514具有作为粘缸剂使用的潜力。

     

    Abstract: In this study, waterborne polyamide(PA236) was synthesized using adipic acid and diethylene triamine. Then, the modified PA236 was obtained by grafting waterborne epoxy resin onto PA236G. Finally, after adding a certain amount of hydroxyethyl cellulose and waterborne curing agent 906 to the PA26G, the waterborne adhesive CA514 was obtained. The structure and relative molecular weight of PA236 and PA236G were characterized by FT-IR, NMR and GPC. The results confirmed the successful synthesis of the PA236 and the grafting of waterborne epoxy. TG analysis was used to determine the thermal properties of these two products, indicating that they could be used as the raw materials for creping adhesive. The properties of the film formed by CA514 were tested. The results showed that the film formed by drying CA514 had similar properties to those of the commercial products, while it has better water resistance with an average swelling degree of 188.3%. The mechanical tests showed that the average shear strength of CA514 could reach 0.122 MPa, which was about twice as that of commercial products, and the CA514 adhesion of substrate was 136.55 N, which was about 1.4 times than that of commercial products. The result indicated that CA514 had the potential to be used as cylinder adhesive.

     

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