高级检索+

杉木间伐材热降解处理制取吸油材料的研究

PREPARATION OF OIL-SORBING MATERIAL FROM INTERMEDIATE CUTTING WOOD OF CHINESE FIR BY THERMO-DEGRADATION

  • 摘要: 以杉木间伐材为原料,经蒸煮、纤维帚化疏解、热降解处理制备出植物纤维吸油材料。研究了吸油材料的吸油性能及其与热处理温度、抽出物的关系等问题。结果表明,经过350℃热处理试样的吸油量最大、吸水量最小,吸油量与吸水量之比值最大,高达77.5,是原料用蒸煮纤维的10倍以上,显示出卓越的吸油性能。蒸煮纤维在200~500℃热处理时,试样的热水抽出物与1% NaOH抽出物含量随热降解温度升高而减少,苯醇抽出物含量则在200~250℃时减少,300℃时增大,400℃后急剧减少。研究表明,纤维表面的亲油性物质对吸油能力有重要影响。制备过程中的热水、苯醇抽出物等的生成、分解、挥发对其选择性吸油能力影响较大,亲油性物质在热降解过程中生成并附着于纤维表面使吸油材料的亲油性提高。

     

    Abstract: Oil-sorbing material was prepared from intermediate cutting wood of Chinese fir by processes comprised of wood cooking,mechanical fibrillating and thermo-degradation.Relations between oil-sorption properties of the product and temperature,extract content were studied.Water sorption of heat-treated fiber decreased when temperature increased.Oil-sorption(except at 350℃) showed much the same pattern,but the selectivity for oil was increased.Hot water and 1% NaOH extracts decreased with increasing temperature.Ethanol-benzene extracts decreased at 200-250℃ and then increased at 300℃.Significant decreases of ethanol-benzene extracts occurred at 400℃,which were caused by (secondary) decomposition and volatilization of these products.These results indicate that oil selectivity of the heat-(treated) wood fiber depends on the increased hydrophobicity of polysaccharides and decreased hydrophilic components.The adhesion of lipophilic pyrolyzate on the fiber surface greatly affects oil selectivity.

     

/

返回文章
返回