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竹材苯酚液化及胶黏剂制备工艺

Technologies of Liquefaction of Bamboo and Preparation of Adhesive

  • 摘要: 采用单因素试验和正交试验研究了竹材加工剩余物的苯酚液化工艺,并进一步研究了竹材苯酚液化产物-甲醛树脂胶黏剂(BPF)的制备工艺和性能.试验结果表明:竹材苯酚液化过程中,液化温度对液化效果的影响最为显著,其次是液比和液化反应时间,催化剂用量2%~4%范围内对液化效果影响不大.竹材加工剩余物苯酚液化的优选工艺为:液固比值3.5、催化剂用量4%、液化温度145℃、液化时间0min;在此工艺下竹材液化率为99.1%.胶黏剂制备过程中,竹材苯酚液化物与甲醛溶液(甲醛质量分数为37%)的合理质量比为100:14.8~199.5,其中以100:182.1较佳.BPF的固化温度低于普通酚醛树脂胶黏剂(PF),因而可在较低温度下固化良好,在130℃或140℃热压温度条件下,用其制备的胶合板的胶合强度均比较理想,热压温度为140℃时的试验结果更佳.

     

    Abstract: The technology of liquefying processed-waste bamboo with phenol is researched by single factor trial and orthogonal trials; and the preparation technology and properties of the adhesive from this phenol-liquefied bamboo with formaldehyde(BPF) are studied. The results testify that temperature is significant on liquefaction, mass ratio of phenol to bamboo is in the next place, catalyst dosage within the range of 2%-4% is less effective. The optimum conditions of liquefaction are as follows: mass ratio of phenol to bamboo 3.5, catalyst dosage 4%, liquefying temperature 145℃, and liquefying time 60 min. Liquifaction rate of bamboo arrived 99.1%. For the preparation of the adhesive, mass ratio of liquefied bamboo products to formaldehyde(37%) is 100 to 164.8-199.5,while the ratio 100 to 108.2 is the best. This adhesive has a lower curing temperature than that of normal PF resin. At the hot-press temperature of 130℃ or 140℃, this new adhesive can provide excellent bond strength of the plywood, and the favorable temperature is 140℃.

     

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