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乙酸乙酯混合溶剂精制塔拉单宁工艺研究

Refining of Tara Tannin with Ethyl Acetate Mixed Solvent

  • 摘要: 用乙酸乙酯萃取精制粗塔拉单宁,粗单宁、水、乙酸乙酯之比1:1.5:4(g:mL:mL),60 ℃ 下萃取 30 min,其单宁得率为 40.2 %,单宁纯度 80.4 %,得率与纯度均偏低。用乙酸乙酯二次萃取其残留水相得率也偏低。对粗制的塔拉单宁用乙酸乙酯与S溶剂(体积比4:1)混合溶剂进行精制,其最佳工艺条件是:料液比为m(粗单宁):V(水):V(混合溶剂)1:1.5:5(g:mL:mL),萃取温度 60 ℃,萃取时间 30 min。在该工艺条件下产品得率 68.2 %,单宁纯度 86.0 %,单宁提取率 87.7 %,得率和纯度都有提高。

     

    Abstract: Crude tara tannin was extracted by water and ethyl acetate at 60 ℃ for 30 min.The ratio of crude tannin-water-ethyl acetate was 1:1.5:4(g:mL:mL). The yield of product was 40.2 % and the purity of tannin was 80.4 %. Both yield and purity are low. The yield was still low when ethyl acetate was used to extract the recidual water phase. Refining tara tannin with mixed solvent of ethyl acetate and S-solvent (4:1) was studied. The optimum conditions are: solid to liquid ratio of m(crude tara tannin):V(water):V(mixed solvent)1:1.5:5(g:mL:mL), extraction temperature 60 ℃,extraction time 30 min. Under this condition, the yield of product was 67.1 %-69.0 %, the purity of tannin was 85.3 %-86.5 %, the extraction rate of tannin was 87.2 %-88.6 %. The yield and purity has been improved.

     

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