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催化氢化3-蒈烯合成蒈烷反应的研究

Synthesis of Carane by Catalytic Hydrogenation of 3-Carene

  • 摘要: 研究了某些特殊松节油中的成分3-蒈烯在带机械搅拌高压釜中制备蒈烷的反应。用Raney Ni与Pd/C作为催化剂,在用量 4 %~10 %、3~12 h、60~180 ℃和3~9 MPa 区间进行单因素试验得到的优化反应条件为:催化剂Raney Ni用量为3-蒈烯质量的 6 %,在温度 100 ℃ 与压力 9 MPa 反应 3 h,3-蒈烯转化率 99.5 %,目的产物蒈烷的平均产率为 96.7 %,蒈烷选择性为 92.8 %。

     

    Abstract: Hydrogenation of 3-carene which is a component of some special turpentine to prepare carane was studied in an autoclave with a mechanical stirrer. The single factor experiment was carried out, while Raney Ni and Pd/C were used under the conditions of catalysts dosage of 4 %-10 %, time 3-12 h, temperature 60-180 ℃ and the hydrogen pressure 3-9 MPa. It resulted in the optimal reaction conditions as 6 % of Raney Ni based on the mass of 3-carene, pressure 9 MPa, temperature 100 ℃, and time 3 h. At these conditions, the yield of carane reached 96.7 % with a selectivity of 92.8 % and a conversion rate of 99.5% of carene.

     

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