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决明子中蒽醌类化学成分的研究

Study on Anthraquinone Constituents in the Seed of Cassia tora L.

  • 摘要: 对决明子中蒽醌类化学成分进行了研究。采用硅胶柱色谱从决明子氯仿萃取物中分离得到7种蒽醌化合物,通过化学和波谱分析方法分别鉴定为:大黄酚(Ⅰ)、大黄素甲醚(Ⅱ)、大黄素(Ⅲ)、黄决明素(Ⅳ),大黄酚-8-甲醚(Ⅴ)、大黄素-1-甲醚(Ⅵ)、1,2-二甲氧基-8-羟基-3-甲基-9,10-蒽醌(Ⅶ)。化合物Ⅴ~Ⅶ为首次从该属植物中分得。

     

    Abstract: Anthraquinone constituents in the seed of Cassia tora L. were investigated. Seven anthraquinone compounds were isolated from chloroform extract of the seed of C. tora with silicagel column chromatography. Their structures were elucidated through physiochemical and spectral analyses. They were identified to be chrysophanol (Ⅰ), physcion (Ⅱ), emodin (Ⅲ), chryso-obtusin (Ⅳ), 8-O-methylchrysophanol (Ⅴ), 1-O-methylemodin (Ⅵ) and 1,2-dimethoxy-8-hydroxy-3-methyl-9,10-anthraquinone (Ⅶ). Compounds Ⅴ-Ⅶ were obtained from thisgenus of plant for the first time.

     

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