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活性炭气相吸附过程中安全性研究进展

Research Progress on the Safety of Activated Carbon in Gas Phase Adsorption Process

  • 摘要: 挥发性有机物(VOCs)是目前我国造成大气污染的主要因素,主要来源于工业排放,VOCs包括烃、醛、醇、醚、酮、酯、羧酸等。活性炭吸附VOCs已成为目前的主要环保技术,然而,在活性炭吸附VOCs过程中,由于吸附热的产生容易导致活性炭床层温度升高,从而引发活性炭床层起火是重大安全隐患。因此,本文从活性炭的结构、性质,吸附操作方式和条件,以及VOCs组分等方面,具体综述和分析活性炭的生产原料、制备方法和后处理过程等影响活性炭着火点的主要因素,以及气流的湿度、氧气含量等性质,气体流速、活性炭床层厚度、吸附工况等吸附工艺对活性炭床层温升产生的影响,为系统掌握和评价活性炭在气相吸附过程中应用安全性提供了参考。在此基础上,针对活性炭吸附床吸附净化含VOCs废气的安全使用提出了具体的建议。最后,指出了在该领域还存在的主要技术问题。

     

    Abstract: Volatile organic compounds(VOCs) were the major reason for air pollution in China, mainly from industrial emissions, containing hydrocarbon, aldehydes, alcohols, ethers and ketones, etc. The granular activated carbon is often applied in the fixed bed. When the activated carbon adsorbs the VOCs, the adsorption heat is released. VOCs adsorption by activated carbon had became the main environmental protection technology at present. However, in the process of VOCs adsorption by activated carbon, the generation of adsorption heat could easily lead to the increase of activated carbon bed temperature, resulting in the fire of activated carbon bed that was a major safety hazard. Therefore, this paper reviewed and analyzed the main factors affecting the ignition point of activated carbon, such as the raw materials, preparation methods and post-treatment processes of activated carbon, from the aspects of the structure and properties of activated carbon, adsorption operation methods and conditions, and VOCs components. The effects of adsorption process such as air humidity, oxygen content, gas flow rate, activated carbon bed depth, and adsorption conditions on the temperature rise of activated carbon bed provided a reference for systematically mastering and evaluating the application safety of activated carbon in gas phase adsorption process. Finally, the main technical problems in this field were pointed out.

     

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