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适量木炭粉改善环氧树脂复合材料热/力学性能

Suitable charcoal loadings improving heat-resistance and mechanical properties of epoxy resins composites

  • 摘要: 为了充分利用木材炭化物,扩大其在复合材料等方面的应用范围,该文采用炭化后的木粉(木炭粉)和环氧树脂,通过模压工艺制备了木炭/环氧树脂复合材料。借助扫描电镜、万能材料试验机、动态热机械分析仪和维卡软化点测量仪等研究木炭粉质量分数对木炭/环氧树脂复合材料弯曲性能、冲击强度、动态力学性能以及耐热性的影响。在环氧树脂中,环氧树脂、反应性稀释剂和固化剂质量比为3∶2∶5;在木炭/环氧树脂复合材料中,木炭粉质量分数分别为0,5%,10%,20%,30%和40%。复合材料固化温度和时间分别设定为100℃和3 h。结果表明,添加木炭粉能有效增强环氧树脂力学性能:与纯环氧树脂相比,弯曲强度和冲击强度最高增加了278%和135%。动态力学性能结果证实随着木炭粉质量分数的增加,复合材料的储能模量和玻璃化转变温度(Tg)也逐渐增加。此外当木炭粉质量分数从0增加到40%时,复合材料的耐热性逐渐提高;维卡软化点从81.2℃提高到274℃。研究结果为,当木炭粉质量分数在10%时,环氧树脂/木炭复合材料具有较佳的力学性能和较好的耐热性能,为木炭在复合材料领域中的应用提供有益的借鉴。

     

    Abstract: Abstract: Wood-plastics composite (WPC) is a new kind of composite material, booming at home and abroad in recent years. It includes 2 types: one is the composite produced directly using extrusion and injection methods based on biomass materials such as wood powder, bamboo powder and hemp fiber; the other is based on carbonized biomass materials, which is fabricated by carbonizing biomass materials at high temperature and then compounding with polymer. The former has been studied in detail, but the latter is scarce. So in this paper, we prepared the charcoal/epoxy composites using compressing method. The effects of charcoal content on the mechanical properties and the heat resistance of charcoal/epoxy composites were investigated using scanning electron microscope (SEM), material testing machines, dynamical thermal mechanical analyzer (DMA) and Vicat softening temperature (VST) measuring instrument. The epoxy, diluents and curing agent at weight ratio of 3:2:5 were used to yield charcoal/epoxy composites. The weight fraction of charcoal in composite was set to 5%, 10%, 20%, 30% and 40%, and the curing temperature and curing time were 100℃ and 3 h, respectively. The results showed that the charcoal in composites, acting as physical cross-link, could improve the mechanical properties of epoxy resins. The flexural strength of composites increased from 10.1 to 38.2 MPa as charcoal loading increased from 0 to 10%, but it started to reduce when charcoal loading exceeded 10%. Like flexural strength, the impact strength of composites also increased from 8.7 to 20.5 kJ/m2 within 10% charcoal loading. However, the flexural modulus of composites increased with charcoal loading increasing till 30%. At high charcoal content, due to the poor wetting properties of charcoal, the mechanical properties of composites began to decrease. The DMA results confirmed that the glass transition temperature of epoxy resins was elevated from 37.5℃ to 60.5℃ as charcoal loading increased from 0 to 10%, indicating strong interaction between epoxy and charcoal. When charcoal loading exceeded 10%, the glass transition temperature started to decline, but it was still higher than that of net epoxy resins. The addition of charcoal improved the heat resistance of epoxy composites, and the VST of charcoal/epoxy composites increased linearly with the increasing of charcoal loading. The 10% charcoal made the VST of epoxy resins increase from 81.2℃ to 126.6℃. Further elevating the charcoal loading caused the VST of composites to exceed 200℃. The results indicate that the charcoal/epoxy composites have better mechanical properties and heat resistance with the charcoal loading of 10%.

     

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