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水热处理对猪粪残渣燃料特性及水热处理系统能量的影响

Effects of hydrothermal treatment on the fuel characteristics of swine manure residue and the energy distribution of hydrothermal treatment system

  • 摘要: 为了解决集中排放的畜禽粪便对环境造成的严重威胁,旨在将其合理利用以减少环境污染。该研究选取畜禽粪便中产量最大的猪粪作为原料,经180~260 ℃水热处理后制得水热残渣,通过元素分析、工业分析、热重试验等方法,探究了水热处理对残渣燃料特性和燃烧性能的影响。在此基础上,采用Aspen plus软件对其水热处理系统进行了能量分析。结果表明:水热处理可显著改善原料的脱水性能,提高了处理后残渣的碳元素、固定碳含量及其低位热值,提高了燃料比,降低氢碳比和氧碳比,产生的残渣性质与褐煤相近。水热处理提高了残渣的着火温度,缩小了燃烧温度范围,有利于残渣的燃料应用。水热处理系统在230 ℃下处理12500 kg的猪粪,系统产生的能量在满足水热过程消耗外,尚余833.49 MJ的能量可对外供热。研究结果可为猪粪水热处理技术的工业化应用提供理论支撑。

     

    Abstract: With the gradual development of large-scale and intensive animal husbandry in China, a large number of concentrated discharge of livestock and poultry manure has posed a serious threat to the environment, and the rational disposal of the waste can effectively avoid environmental pollution. As the traditional disposal methods, aerobic composting and anaerobic fermentation have their own limitations. As a more reasonable technical route, hydrothermal treatment technology has attracted more and more attention because it is beneficial to the high-value and harmless utilization of livestock and poultry manure. Based on the above background, the swine manure with the largest yield was selected as raw material, and the hydrothermal residue was prepared by 180~260 ℃ hydrothermal treatment (the residence time is 0 min) with the solid-liquid ratio at 1:12 (in dry basis). The effects of the hydrothermal treatment on the moisture content, hydrothermal residue yield, fuel characteristics and combustion performance of the hydrothermal residue were studied by means of elemental analysis, industrial analysis and thermogravimetric experiment. Based on the experimental results, the hydrothermal treatment system was simulated by Aspen plus software and the influence of hydrothermal temperature on the steam supply and demand of the system is explored. The results show that the hydrothermal treatment can improve the dehydration performance of the hydrothermal residues. The moisture content of the wet hydrothermal residue decreases gradually with the increasing hydrothermal temperature. Hydrothermal treatment improves the quality of the residue as fuel. Compared with the raw materials, the carbon content of the residue after hydrothermal treatment can be increased by 4.6% to 8.0%, the fixed carbon content increases by 21.9% to 79.4%, the low calorific value increases by 5.2% to 19.6%, and fuel ratio increases by 27.3% to 172.7%. Hydrothermal treatment reduces the hydrogen-carbon ratio and oxygen-carbon ratio of the raw material, which deepens the carbonization degree of the raw material, and the fuel performance of the residue is similar to that of lignite. The hydrothermal treatment increases the ignition temperature of the residue and reduces the combustion temperature range, which is beneficial to the application of the hydrothermal residue as fuel. In the hydrothermal treatment system, part of the flash steam produced by the pressure relief of the swine manure after hydrothermal treatment was used for the drying of wet hydrothermal residue, and the rest was used for the raw swine manure preheating in the early stage to increase the temperature of the raw swine manure and reduce the moisture content of the wet hydrothermal residue into the furnace. The output steam of the swine manure hydrothermal treatment system at 230 ℃ is the largest. Therefore, the energy consumption of swine manure hydrothermal treatment system at 230 ℃ was analyzed. The hydrothermal treatment system for 12500 kg swine manure was designed under 230 ℃. The energy generated by the system can not only meet the consumption of the hydrothermal process, but also supply 833.49 MJ for external heating.

     

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