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煳化温度及停留时间对厨余垃圾煳化热解产物理化性质的影响

Influence of gelatinization temperature and residence time on the characteristics of kitchen waste gelatinization products

  • 摘要: 为明确厨余垃圾煳化热解的最佳煳化温度和停留时间参数,该研究以厨余垃圾为原料,采用中低温、贫氧煳化热解技术,分别设置煳化温度梯度(150、175、200、225、250、275 ℃)与停留时间梯度(1.0、1.5、2.0、2.5、3.0、3.5 h)进行试验,进一步分析煳化温度及停留时间对产物产率、理化性质、养分含量及种子发芽指数的影响。结果表明,在煳化温度梯度下,随着煳化温度升高,产物的含水率逐渐降低,灰分含量逐渐上升;pH、总有机碳、阳离子交换量以及氮磷钾养分、发芽指数整体表现为先上升后下降的变化趋势,且上述指标在煳化温度200 ℃下达到峰值。在停留时间梯度下,随着停留时间的延长,产物的理化性质与发芽指数同样呈现先上升后降低的变化特征;当停留时间为2.5 h时,总养分、阳离子交换量等指标取得最优值。同时,借助响应面法及回归方程模型进一步分析各试验因素,分析结果表明煳化温度与停留时间对产物的理化性质具有显著的协同影响;且在操作可行性范围内,认为煳化温度200 ℃、停留时间2.5 h是该研究中厨余垃圾煳化热解的最佳工艺参数,在该参数下厨余垃圾煳化产物兼具良好的稳定性和农业应用潜力,这为优化厨余垃圾煳化热解工艺和推进厨余垃圾高值化、无害化、资源化利用提供了理论依据与实践参考。

     

    Abstract: To determine the optimal gelatinization temperature and residence time parameters for the pyrolysis of food waste, this study used unsieved food waste as raw material and applied a medium-to-low temperature, oxygen-limited gelatinization pyrolysis technology. A series of experiments were conducted with varying gelatinization temperatures (150, 175, 200, 225, 250, and 275 ℃) and residence times (1.0, 1.5, 2.0, 2.5, 3.0, and 3.5 h), to analyze the effects of these parameters on product yield, physicochemical properties, nutrient content, and seed germination index. The results showed that within the set process parameters, with the increase of gelatinization temperature and residence time, the yield of gelatinization products of kitchen waste showed a significant downward trend, the moisture content gradually decreased, while the ash content of the products continued to rise. Regarding the physicochemical properties and biological indicators of the gelatinization products of kitchen waste, the pH, electrical conductivity, total organic carbon, cation exchange capacity, seed germination index and nutrient content of nitrogen, phosphorus and potassium of the products all showed a trend of first increasing and then decreasing. In contrast, the H/C, O/C and C/N ratios of the products showed a trend of first decreasing and then increasing. The above indicators showed obvious turning points at a gelatinization temperature of 200 ℃ and a residence time of 2.5 h, indicating that the total organic carbon, cation exchange capacity, total nutrient content and the content of trace elements such as calcium, magnesium, copper, zinc, iron and manganese of the gelatinization products of kitchen waste reached their peaks at this point. Specifically, the total organic carbon reached 531.80 g/kg and 632.53 g/kg respectively at a gelatinization temperature of 200 ℃ and a residence time of 2.5 h; the cation exchange capacity was 203.29 cmol/kg and 203.38 cmol/kg respectively under the above conditions; the total nutrient content was 106.18 g/kg and 114.93 g/kg respectively. At the same time, the seed germination index of the gelatinization products of kitchen waste was the highest at a gelatinization temperature of 200 ℃ and a residence time of 2.5 h, reaching 81.86% and 72.37% respectively, indicating that the products prepared under these conditions showed good stability and reliable biological safety. Using response surface methodology and regression models, the significant synergistic effects of gelatinization temperature and residence time on the properties of the pyrolyzed product were further revealed. The optimized conditions predicted by the response surface model were 201 ℃ and 2.47 h, corresponding to predicted TOC and TNC values of 622.46 and 114.06 g/kg, respectively. However, considering operational feasibility within the experimental parameter range, the gelatinization temperature was adjusted to 200 ℃ and residence time to 2.5 h for validation. The measured values deviated from the predicted values by 10.04 and 0.84 g·kg-1 for TOC and TNC, respectively: deviations within acceptable limits. Therefore, 200 ℃ and 2.5 h were identified as the optimal process parameters for food waste gelatinization pyrolysis in this study. The resulting gelatinized product demonstrated excellent performance in terms of physicochemical properties, nutrient enrichment, environmental safety, and structural characteristics, showing both high stability and strong agricultural application potential. These findings provide theoretical support and practical guidance for optimizing food waste gelatinization pyrolysis processes and promoting high-value, harmless, and resource-efficient utilization of food waste.

     

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