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POE/SBS复合改性沥青高低温流变及疲劳性能研究

Study on Rheological and Fatigue Properties of POE/SBS Composite Modified Bitumen at High and Low Temperature

  • 摘要: 为解决苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)改性沥青热氧和光氧老化的问题,本研究以聚烯烃弹性体(Polyolefin elastomer, POE)为改性剂,分别加入2%、3%、4%和5%的掺量对SBS改性沥青进行复合改性,以研发一种新型高性能POE/SBS沥青。通过采用布氏黏度试验(Rotation Viscosity, RV)、频率扫描(Frequency sweep,FS)和温度扫描(Temperature sweep,TeS)、多应力蠕变恢复试验(Multiple Stress Creep Recovery test, MSCR)、线性振幅扫描试验(Linear Amplitude Sweep, LAS)和低温弯曲梁流变试验(Bending Beam Rheological test, BBR),对POE/SBS复合改性沥青老化前后流变性能进行对比分析。研究结果表明,POE的掺入可显著提升SBS沥青高温抗变形能力、弹性恢复性能,但却对低温和疲劳性能有轻微不利作用。综合沥青胶结料各性能要求, POE/SBS复合改性沥青的最佳配比为4%SBS+3%POE+0.1%硫磺。

     

    Abstract: In order to solve the problem of thermal oxidation and photooxidative aging of styrene-butadiene-styrene triblock copolymer(SBS) modified bitumen, polyolefin elastomer(POE) was used as modifiers in this study, and 2%, 3%, 4% and 5% of SBS modified bitumen were compound modified to develop a new type of high-performance POE/SBS bitumen. Through Brookfield viscosity test(RV), frequency sweep( FS) and temperature sweep( Te S), multiple stress creep recovery test( MSCR), linear amplitude sweep test(LAS) and bending beam rheological test(BBR), the rheological properties of POE/SBS composite modified bitumen before and after aging were studied and evaluated. The results showed that the addition of POE significantly improved the high-temperature deformation resistance and elastic recoverability, while had a negative effect on the low temperature and fatigue performance of SBS modified bitumen. This study indicated that considering all the performance requirements of modified bitumen, the optimum mix proportion of POE/SBS modified bitumen was as follows: 4%SBS+3%POE+0. 1% Sulphur.

     

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