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麦渣与制浆废液共混制备成型颗粒燃料及其燃烧特性分析

Analysis on Combustion Characteristics of Pellet Fuel Prepared by Blending Wheat Residue and Pulping Waste Liquid

  • 摘要: 为研究麦渣与制浆废液共混制备的成型颗粒燃料的燃烧特性, 通过热重分析法对其燃烧热力学及燃烧动力学进行了研究。结果表明: 制浆废液的添加使颗粒燃料出现固定碳的二次燃烧阶段, 有利于降低成型颗粒燃料的挥发分、固定碳燃烧阶段的点火温度及最大燃烧速率温度, 对颗粒燃料的燃烧有正向协同作用; 制备的颗粒燃料的一阶动力学模型拟合曲线的相关系数在0.95以上, 颗粒燃料在挥发分燃烧和固定碳燃烧阶段的活化能和指前因子均随制浆废液的添加而降低。当废液固形物质量分数为53%时制备的成型颗粒燃料, 其挥发分燃烧阶段和固定碳燃烧阶段的活化能为72.85和83.52kJ/mol, 指前因子为2.82×106和3.73×105min-1。制浆废液的添加使颗粒燃料更易燃烧, 且燃烧过程稳定不易爆燃。

     

    Abstract: In order to study the combustion characteristics of pellet fuel prepared by blending wheat residue and waste liquid in pulping process, the combustion thermodynamics and kinetics characteristics were analyzed by thermogravimetric test. The results showed that pulping waste liquid resulted in the secondary combustion stage of fixed carbon in the pellet fuel. The addition of pulping waste liquid was helpful to decrease the volatile content of pellet fuel, the ignition temperature, and maximum combustion rate temperature in the fixed carbon combustion stages, which had a positive synergistic effect on the combustion of pellet fuel. The thermogravimetric data were fitted with a first-order dynamics equation, and the correlation indexes of the prepared pellet fuel were all above 0.95. The addition of the pulping waste liquid reduced the activation energy and frequency factors of the pellet fuel in the volatile combustion and fixed carbon combustion stages, respectively. The activation energies of the corresponding stage when a solid mass fraction of 53% of the waste liquid were 72.85 and 83.52 kJ/mol, and the frequency factors were 2.82×106 and 3.73×105 min-1, respectively. The addition of the pulping waste liquid made the pellet fuel easier to burn, and the combustion process became stable and uneasy to deflagrate.

     

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