WANG Ji-fu, CHANG LI-li, YU Juan, NAN Jing-ya, LIU Yu-peng, LIN Ming-tao, WANG Chun-peng, LIU Mei-hong, CAI Zhi-hui, CHU Fu-xiang. Synthesis,Characterization and Properties of Allyl Ester of Maleopimaric Acid[J]. Biomass Chemical Engineering, 2012, 46(3): 1-4.
Citation: WANG Ji-fu, CHANG LI-li, YU Juan, NAN Jing-ya, LIU Yu-peng, LIN Ming-tao, WANG Chun-peng, LIU Mei-hong, CAI Zhi-hui, CHU Fu-xiang. Synthesis,Characterization and Properties of Allyl Ester of Maleopimaric Acid[J]. Biomass Chemical Engineering, 2012, 46(3): 1-4.

Synthesis,Characterization and Properties of Allyl Ester of Maleopimaric Acid

  • Allyl ester of maleopimaric acid (MA-BXC) with a purity of 99.2% was prepared by the reaction between maleopimaric acyl chloride and allyl alcohol with the yields near to 70%. The structure and properties of MA-BXC was evaluated by FT-IR spectroscopy, GC-MS, 13C NMR spectroscopy and DSC. The results indicated that MA-BXC was an allyl monomer with anhydride group and can be polymerized while being heated to above the melting point. The glass transition temperature of MA-BXC's homopolymer is about 98℃. These results showed that MA-BXC had a great potential to be used as a precursor of unsaturated resin and epoxy resin.
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