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硫酸盐和氯盐对砂浆宏微观力学性能的影响

Macro-and micro-mechanical properties of mortar under sulfate and cloride attack

  • 摘要: 盐湖和海水中富含的硫酸盐和氯盐会从外向内侵蚀混凝土结构。针对硫酸盐和氯盐侵蚀的不均匀特性,通过开展不同侵蚀工况下的X射线衍射、抗压强度、劈裂抗拉强度和不同侵蚀深度的维氏硬度试验,探究不同侵蚀程度下砂浆试样的物相组成和宏、微观力学性能的演变规律,并改进Logistic函数建立维氏硬度评估模型。结果表明:复合盐侵蚀下硫酸盐和氯盐的侵蚀产物减少;复合盐侵蚀下维氏硬度沿深度的分布可分为上升段、下降段和稳定段3部分;建立的评估模型能够准确描述硫酸盐和氯盐侵蚀下砂浆维氏硬度的分布规律;维氏硬度可以用于分析不同侵蚀深度材料抗压性能的演变规律。研究成果可为混凝土结构的耐久性评估和修复提供参考。

     

    Abstract: Salt lakes and seawater contain a large amount of sulfates and chlorides, which can cause degradation of underwater concrete structures from the outer surface to the inner core. According to the heterogeneous corrosion characteristics of mortar under sulfate and chloride attack, a series of tests, including X-ray diffraction, compressive strength, splitting tensile strength and Vickers hardness tests, were conducted on samples exposed to different corrosion conditions to investigate the evolution of phase composition and macro-and micro-mechanical properties of mortar. A Vickers hardness evaluation model was developed by modifying Logistic function. The results revealed that the corrosion products of sulfate and chloride decreased under combined sulfate and chloride attack. Moreover, the distribution of Vickers hardness along depth under combined attack could be divided into three phases, namely, ascending, descending and stable phase. The proposed evaluation model accurately described the Vickers hardness distribution of mortar in sulfate and chloride environment. Additionally, Vickers hardness was shown to be effective in analyzing the evolution of compression resistance in different corrosion depths. The research findings could provide some reference for durability evaluation and restoration of concrete structures.

     

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