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基于FeS2及其复合材料的钠离子电池负极材料的研究进展

Research Progress of FeS2 and Its Composites as Anode Materials for Sodium Ion Batteries

  • 摘要: 二硫化亚铁(FeS2)具有高理论比容量、高电导率、价格低廉以及环境友好的优势,被视为是一种非常具有发展前景的钠离子电池负极材料。然而,FeS2作为钠离子电池负极材料在其充放电过程中体积变化较大,反应动力学较迟缓,进而展现为电化学性能不佳,这严重制约了其在钠离子电池中的大规模应用。因此,总结FeS2材料在钠离子电池循环过程中的反应机理,归纳既有研究对FeS2负极材料瓶颈问题的解决方式,探讨了未来提升FeS2负极材料性能可行的工作方向,对设计高容量的钠离子电池至关重要。本文首先阐述了FeS2负极材料的结构特性与储钠机制;其次,根据FeS2的反应机制及物理特性,总结了FeS2作为钠离子电池负极材料的瓶颈问题;然后,从FeS2的结构调控、 FeS2/碳基复合材料、 FeS2/高分子化合物复合材料及FeS2/金属化合物复合材料四个方面归纳了近年来既有研究瓶颈问题的解决方案;最后,基于上述分析,从强化电解质特性、调控电极结构、降低材料成本、改变电极基底及优化电池工作环境的角度提出未来提升FeS2负极材料钠离子电池性能的可行性工作方向。

     

    Abstract: Ferrous disulfide(FeS2) is regarded as a promising anode material for sodium-ion batteries because of its high theoretical specific capacity, high conductivity, low price, and environmental friendliness. However, as a cathode material for sodium-ion batteries, FeS2 shows a large volume change and sluggish reaction kinetics during battery charging and discharging processes exhibits poor electrochemical performance due to its large volume change during charging and discharging processes, this poor electrochemical performance of FeS2 seriously limits its large-scale application in sodium-ion batteries. Summarizing the reaction mechanism of FeS2 materials during the sodium-ion batteries working process, reviewing the studies of the solutions to the bottleneck of FeS2 cathode material in sodium-ion batteries, and exploring the future works to enhance the performance of FeS2 are crucial for the design of high-capacity sodiumion batteries. From this point of view, this paper firstly described the structural properties and sodium storage mechanism of FeS2 cathode materials; then, the bottlenecks of FeS2 as an anode material for sodium-ion batteries were summarized based on the reaction mechanism and physical properties of FeS2; subsequently, solutions to the bottlenecks of FeS2 anode reported in recent years were summarized from four aspects, including the structure modulation of FeS2, FeS2/carbon composites, FeS2/polymer composites and FeS2/metal-compound composites; finally, based on the above analysis, some feasible ways to enhance the performance of sodium-ion batteries with FeS2 cathode material were also provided, which include enhancing the electrolyte properties, regulating the electrode structure, reducing the cost, changing the electrode substrate, and optimizing the working environment of the batteries.

     

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