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超重力-水热法制备形貌可控的钛酸锶钡粉体

Preparation of Barium Strontium Titanate Powder with Controllable Morphology by High-Gravity and Hydrothermal Method

  • 摘要: 零维和多维结构的钛酸锶钡(Ba1-xSrx TiO3, BST)粉体分别具有高比表面积和高长径比的优势,为提升材料性能并扩大电子元件中原材料的工业化应用,改善粉体制备过程中分布不均、耗时长的问题,采用撞击流-旋转填料床(IS-RPB)结合水热法制备了添加丙三醇的BST粉体,考察了水热温度、水热时间及丙三醇添加量等因素对BST粉体形貌的影响规律。结合X-射线衍射仪(XRD)、扫描电子显微镜(SEM)以及透射电子显微镜(TEM)对BST粉体的形貌、晶相及组成进行了表征分析。结果表明:在超重力因子为40、撞击初速度10.61 m/s、水热温度180℃、水热时间12 h的条件下,当添加少量丙三醇时,其充当分散剂的作用,所制得的BST粉体为均匀性与分散性良好的纳米球形颗粒;当添加较多丙三醇时,其充当溶剂的作用,在水热条件下沿单元晶面生长得到了片状及花状形貌。本文提出的超重力-水热法及丙三醇的添加对于工业化形貌可控制备BST粉体探索提供了一种方便快捷的途径。

     

    Abstract: Zero-dimensional and multidimensional structures of barium strontium titanate(Ba1-xSrx TiO3, BST) powders have the advantages of high specific surface area and high aspect ratio, respectively. To improve the material properties, expand the industrial application of raw materials in electronic components and improve the uneven distribution and long time in the preparation process of powder, BST powder with glycerol were prepared by impinging stream-rotating packed bed(IS-RPB) combined hydrothermal method. The effects of hydrothermal temperature, hydrothermal time and the amount of glycerol added to the morphology of BST powder were investigated. The morphology, crystal phase and composition of BST powder were characterized by X-ray diffractometer(XRD), scanning electron microscope(SEM) and transmission electron microscope(TEM). The results show that under the conditions of supergravity factor of 40, initial impact velocity of 10. 61 m/s, hydrothermal temperature of 180 ℃ and hydrothermal time of 12 h, when a small amount of glycerol is added, it acts as a dispersant, and the BST powder is prepared as nano spherical particles with good uniformity and dispersion. When more glycerol is added, it acts as a solvent and grew along the unit crystal surface under hydrothermal conditions to obtain flake and flower-like morphology. In this paper, the high-gravity hydrothermal method and the addition of glycerol have explored a convenient and fast way for the preparation of BST powder with controllable morphology in industrial industry.

     

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