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聚氨酯用作煤矸石固化材料综合性能研究

Study on comprehensive properties of polyurethane used as curing material of coal gangue

  • 摘要: 针对青海木里矿区露天煤矿风化煤矸石堆场边坡发生优先流现象导致土壤破坏、水土流失以及边坡不稳定等生态环境问题,选用高分子材料聚氨酯作为固化剂,通过固结表层风化煤矸石,达到固化坡面,降低坡面入渗率目的。针对聚氨酯固化煤矸石实际效果及关键影响因素研究尚不充分问题,本研究开展45组不同配比煤矸石—聚氨酯固化试件的单轴压缩试验,60组不同工况煤矸石—聚氨酯固化坡面的人工降雨试验,研究煤矸石—聚氨酯复合材料的主要力学性能、渗透性和技术经济,运用层次分析法对不同配合比进行综合评价,揭示其关键影响因素,筛选最优配比方案。结果表明:1)聚氨酯浓度对提高固化试件的抗压强度贡献最大,而弹性模量主要受煤矸石粒径大小的影响;2)固化煤矸石坡面的平均产流率与聚氨酯浓度成正比,与煤矸石密度成正比,与粒径成反比;平均产沙率与粒径、密度和聚氨酯浓度均成反比;稳定入渗率与粒径成正比,密度与聚氨酯浓度成反比,与密度成反比;3)综合评价45组煤矸石—聚氨酯固化方案,其中最优方案为煤矸石粒径0~0.5 mm、密度1.55 g/cm3,聚氨酯浓度3.5%,该煤矸石—聚氨酯固化方案能够大幅提升坡面的抗压强度,并有效降低入渗性能,同时保持较好的经济性(约17元/m2)。研究结果可为木里煤矿生态修复工程提供重要技术参考。

     

    Abstract:
    Background The Muli mining area is an indispensable water conservation area and the core component of the ecological security barrier in the Qilian Mountains, and its ecological status is extremely important. However, with a large number of excavations, the Muli mining area has accumulated large-scale coal gangue piles. The weathering deposits on the surface of these coal gangue slopes cause preferential flow, resulting in a series of ecological and environmental problems such as soil damage, soil erosion, and slope instability. In order to solve the above ecological and environmental problems, this paper chose Muli mining area as the research area.
    Methods In view of the insufficient research on the actual effect and key influencing factors of polyurethane solidified coal gangue, this study carried out 45 groups of uniaxial compression tests of coal gangue-polyurethane solidified specimens with different proportions, and 60 groups of artificial rainfall tests of coal gangue-polyurethane solidified slopes under different working conditions. The main mechanical properties, permeability and technical economy of coal gangue-polyurethane composites were studied. The analytic hierarchy process was used to comprehensively evaluate different mix ratios, and to reveal the key influencing factors, and screen the optimal mix ratio scheme.
    Results 1) Polyurethane concentration contributed the most to improving the compressive strength of the solidified specimens, while the elastic modulus was mainly affected by the particle size of coal gangue. 2) The average runoff rate of solidified coal gangue slope was proportional to the concentration of polyurethane, proportional to the density of coal gangue, and inversely proportional to the particle size; the average sediment yield was inversely proportional to particle size of coal gangue, density of coal gangue and polyurethane concentration. The stable infiltration rate was proportional to the particle size of coal gangue, and the density of coal gangue was inversely proportional to the polyurethane concentration and inversely proportional to the density.3) The comprehensive evaluation of 45 groups of coal gangue-polyurethane curing schemes was carried out. When the particle size was 0-0.5 mm, the comprehensive evaluation value was 0.260 68-0.725 35. When the particle size was 0.5-1 mm, the comprehensive evaluation value was 0.313 86-0.442 87. When the particle size was 1-2 mm, the comprehensive evaluation value was 0.266 33-0.311 14.
    Conclusions The optimal slope stabilization scheme is coal gangue with the particle size 0-0.5 mm, the density 1.55 g/cm3, polyurethane concentration 3.5% The coal gangue-polyurethane curing scheme may greatly improve the compressive strength of the slope, and effectively reduce the infiltration performance, while maintaining a good economy (about 17 RMB Yuan/m2). The research results have important technical reference for the ecological restoration project of Muli Coal Mine.

     

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